Virosa, AchmadVirdi (2014) Perangkap Polisiklik Aromatik Hidrokarbon (PAH) dalam Emisi Kendaraan Bermotor dengan Menggunakan Whatman Filter Paper PM 2.5. Sarjana thesis, Universitas Brawijaya.
Abstract
Penelitian ini bertujuan untuk menganalisis kandungan Polisiklik Aromatik Hidrokarbon (PAH) yang diemisikan oleh sepeda motor. Sepeda motor yang digunakan dalam penelitian ini antara lain Satria, Beat, Mio Soul, Hayate, dan Vega ZR. Masing-masing sepeda motor tersebut memiliki tahun keluaran 2010 hingga 2011. Penangkapan emisi dari sepeda motor dilakukan dengan mengumpankan emisi pada whatman filter paper PM 2.5. Komponen PAH yang terperangkap pada whatman filter paper PM 2.5 diisolasi dengan metode soxhlet yang dilakukan selama 10 jam. Sedangkan pembersihan ekstrak dilakukan dengan metode kolom kromatografi. Untuk melakukan analisis terhadap komponen PAH digunakan Gas Chromatograohy Mass Spectrophotometer (GC/MS) dengan jenis kolom DB-5ms. Hasil dari GC/MS menunjukkan bahwa adanya 16 jenis senyawa karsinogen yang tergolong dalam PAH dan Volatile Organic Compound (VOC). Senyawa yang terdeteksi dalam emisi sepeda motor tersebut antara lain 2-methyl-naphthalene, acenaphthene, 1-naphthalen-2yl-ethanone, c-(3-vivyl-naphthalen-2- yl)-methylamine, 1-(3-methyl-naphthalen-2-yl)-ethanone, 3-methyl- 1,2,3,4-tetrahydro-anthracen-2-ylamine, benzo[a]anthracene, 9- vinyl-naphthacene-2-carbonitrile, benzophenone, 1,4- dimetilbenzena, 2,3-dimetilpentana, etilbenzena, metilsiklopentana, n-heksana, sikloheksana, dan 2-heksanon. Senyawa dalam golongan PAH dan VOC adalah senyawa yang dapat terbentuk dalam proses pembakaran yang kurang sempurna. Senyawa tersebut bersifat karsinogen sehingga dapat menimbulkan barbagai macam gangguan kesehatan.
English Abstract
This study aims to analyze the content of Polycyclic Aromatic Hydrocarbons (PAHs) emitted by motorcycles. Motorcycle used in this study include Satria, Beat, Mio Soul, Hayate, and Vega ZR. Each motorcycle has the output of the 2010 until 2011. Trapping emissions from motorcycles are done by feeding the emission to whatman filter paper PM 2.5. PAH components were trapped on the filter paper whatman PM 2.5 was isolated by Soxhlet method. The soxhlet method were carried out for 10 hours. Extract cleaning was conducted by column chromatography. Gas Chromatography Mass Spectrofotometer (GC/MS) with a DB-5ms column is used to analyze PAH compound. The results of GC/MS showed that the presence of 7 types of carcinogenic compounds belonging to the PAH and Volatile Organic Compound (VOC). Compounds were detected in motorcycle emissions include 2-methyl-naphthalene, acenaphthene, 1- naphthalen-2yl-ethanone, c-(3-vivyl-naphthalen-2-yl)-methylamine, 1-(3-methyl-naphthalen-2-yl)-ethanone, 3-methyl-1,2,3,4-tetrahydroanthracen- 2-ylamine, benzo[a]anthracene, 9-vinyl-naphthacene-2- carbonitrile, benzophenone, 1,4-dimethylbenzene, 2.3- dimethylpentane, ethylbenzene, methylcyclopentane, n-hexane, cyclohexane, and 2-hexanone. Compounds in the class of PAH and VOC can be formed through the incomplete combustion. These compounds are carcinogenic compounds that can cause health problems.
| Item Type: | Thesis (Sarjana) |
|---|---|
| Identification Number: | SKR/MIPA/2014/336/051405834 |
| Subjects: | 500 Natural sciences and mathematics > 540 Chemistry and allied sciences |
| Divisions: | Fakultas Matematika dan Ilmu Pengetahuan Alam > Kimia |
| Depositing User: | Budi Wahyono Wahyono |
| Date Deposited: | 15 Sep 2014 12:51 |
| Last Modified: | 21 Oct 2021 05:41 |
| URI: | http://repository.ub.ac.id/id/eprint/153970 |
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